Question Details

xCl2 + yOH- → zCl- + pClO- Balance the above reaction and find out values of x, y, z and p.

Options

A

x = 1, y = 2, z = 2, p = 1

B

x = y = z = p = 1

C

x = 1, y = 1, z = 2, p = 1

D

x = 1, y = 2, z = 1, p = 1

Correct Answer :

x = 1, y = 2, z = 1, p = 1

Solution :

To find the correct values of the stoichiometric coefficients x, y, z, and p, we need to balance the given chemical equation:
xCl2+yOH-zCl-+pClO-+H2O

Note: In basic medium, the disproportionation of chlorine (Cl2) produces chloride (Cl-) and hypochlorite (ClO-) ions, along with water (H2O) to balance hydrogen and oxygen.

Let us balance the equation step-by-step using the half-reaction method or by balancing atoms and charges:

1. Balancing Chlorine (Cl) atoms:
The reactant side has 2x chlorine atoms.
The product side has z+p chlorine atoms.
Therefore, we have the relation:
2x=z+p

2. Balancing Oxygen (O) and Hydrogen (H) atoms:
If we have y hydroxide ions (OH-) on the reactant side, we have y hydrogen atoms and y oxygen atoms.
To balance the y hydrogen atoms, we must have y2 water molecules (H2O) on the product side.
Now, balancing the oxygen atoms:
Reactant side oxygen = y
Product side oxygen = p (from ClO-) + y2 (from H2O)
Setting them equal:
y=p+y2y2=py=2p

3. Balancing the net charge:
Total charge on reactant side = -y
Total charge on product side = -z-p
Equating the charges:
-y=-z-py=z+p

4. Solving the equations:
From charge balance: y=z+p
From oxygen/hydrogen balance: y=2p
Equating these two expressions for y:
2p=z+pp=z
Since 2x=z+p, and we know p=z:
2x=p+p=2px=p

Thus, we have:
x=p
z=p
y=2p

Setting the simplest whole-number value p=1, we get:
x=1
y=2
z=1
p=1

Substituting these values back into the reaction gives a fully balanced equation:
Cl2+2OH-Cl-+ClO-+H2O

Therefore, the coefficients are x = 1, y = 2, z = 1, p = 1.

Unlock Our Free Library

Access expert-curated educational resources and study materials—completely free.

Discover more resources

You may also like

Mock Tests

View All
  • JEE
  • intermediate
  • 3 hours
  • chemistry, mathematics, physics

  • JEE
  • intermediate
  • 3 hours
  • chemical engineering, mathematics, physics