xCl2 + yOH- → zCl- + pClO- Balance the above reaction and find out values of x, y, z and p.
Correct Answer :
x = 1, y = 2, z = 1, p = 1
Solution :
To find the correct values of the stoichiometric coefficients x, y, z, and p, we need to balance the given chemical equation:
Note: In basic medium, the disproportionation of chlorine () produces chloride () and hypochlorite () ions, along with water () to balance hydrogen and oxygen.
Let us balance the equation step-by-step using the half-reaction method or by balancing atoms and charges:
1. Balancing Chlorine (Cl) atoms:
The reactant side has chlorine atoms.
The product side has chlorine atoms.
Therefore, we have the relation:
2. Balancing Oxygen (O) and Hydrogen (H) atoms:
If we have y hydroxide ions () on the reactant side, we have y hydrogen atoms and y oxygen atoms.
To balance the y hydrogen atoms, we must have water molecules () on the product side.
Now, balancing the oxygen atoms:
Reactant side oxygen = y
Product side oxygen = p (from ) + (from )
Setting them equal:
3. Balancing the net charge:
Total charge on reactant side =
Total charge on product side =
Equating the charges:
4. Solving the equations:
From charge balance:
From oxygen/hydrogen balance:
Equating these two expressions for y:
Since , and we know :
Thus, we have:
Setting the simplest whole-number value , we get:
Substituting these values back into the reaction gives a fully balanced equation:
Therefore, the coefficients are x = 1, y = 2, z = 1, p = 1.
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