Which of the following sets of quantum numbers represents the highest energy of an atom?

Options :

1. n = 3, l = 0, m = 0, s = + \(\frac {1}{2}\)

2. n = 3, l = 1, m = 1, s = + \(\frac {1}{2}\)

3. n = 3, l = 2, m = 1, s = + \(\frac {1}{2}\)

4. n = 4, l = 0, m = 0, s = + \(\frac {1}{2}\)