Question Details

The ratio of the adiabatic to isothermal elasticities of a triatomic gas is

Options

A

3/4

B

4/3

C

1

D

5/3

Correct Answer :

4/3

Solution :

The correct option is 4/3.

To find the ratio of the adiabatic elasticity to the isothermal elasticity of a triatomic gas, we first determine the mathematical expressions for both elasticities.

Elasticity (or bulk modulus) is defined as the ratio of volume stress to volume strain:
E=-dPdV/V=-VdPdV

1. Isothermal Elasticity (ET):
For an isothermal process, the temperature remains constant. The equation of state is Boyle's Law:
PV=constant

Differentiating both sides with respect to volume:
PdV+VdP=0

Rearranging the terms yields:
-VdPdV=P

Thus, the isothermal elasticity is equal to the pressure of the gas:
ET=P

2. Adiabatic Elasticity (ES):
For an adiabatic process, there is no heat exchange with the surroundings. The equation of state is:
PVγ=constant

Differentiating both sides:
VγdP+γPVγ-1dV=0

Dividing the equation by Vγ-1 gives:
VdP+γPdV=0

Rearranging the terms yields:
-VdPdV=γP

Thus, the adiabatic elasticity is:
ES=γP

3. Ratio of Elasticities:
The ratio of the adiabatic elasticity to the isothermal elasticity is:
ESET=γPP=γ

Here, γ is the ratio of specific heats (Cp/Cv). For a non-linear triatomic gas, the number of degrees of freedom (f) is 6.

The relation between γ and the degrees of freedom f is:
γ=1+2f

Substituting f=6 into the equation:
γ=1+26=1+13=43

Therefore, the ratio of the adiabatic to isothermal elasticities of the triatomic gas is 4/3.

Unlock Our Free Library

Access expert-curated educational resources and study materials—completely free.

Discover more resources

You may also like

Mock Tests

View All
  • JEE
  • intermediate
  • 3 hours
  • chemistry, mathematics, physics

  • JEE
  • intermediate
  • 3 hours
  • chemical engineering, mathematics, physics