Question Details

The outer orbitals of C in ethene molecule can be considered to be hybridized to give three equivalent sp² orbitals. The total number of sigma (s) and pi (p) bonds in ethene molecule is

Options

A

1 sigma (s) and 2 pi (p) bonds

B

3 sigma (s) and 2 pi (p) bonds

C

4 sigma (s) and 1 pi (p) bonds

D

5 sigma (s) and 1 pi (p) bonds

Correct Answer :

5 sigma (s) and 1 pi (p) bonds

Solution :

The correct option is 5 sigma (s) and 1 pi (p) bonds.

To understand why this is correct, let us analyze the structure and bonding of the ethene molecule step-by-step:

1. Structure of Ethene:
Ethene is a hydrocarbon with the molecular formula:

C2H4

It consists of two carbon atoms bonded to each other, with each carbon atom also bonded to two hydrogen atoms. Structurally, it is represented as:

H2C=CH2

2. Hybridization of Carbon:
Each carbon atom in ethene is hybridized as:

sp2

This hybridization is achieved by mixing one 2s orbital and two 2p orbitals, resulting in three equivalent hybrid orbitals aligned in a planar trigonal geometry. One unhybridized 2p orbital remains perpendicular to this plane on each carbon atom.

3. Counting Sigma (σ) Bonds:
Sigma bonds are formed by the head-on overlap of atomic or hybridized orbitals. In ethene, these are formed as follows:
Carbon-Carbon (C-C) overlap: One hybrid orbital from the first carbon atom overlaps head-on with a hybrid orbital from the second carbon atom to form a single C-C sigma bond.
Carbon-Hydrogen (C-H) overlap: The remaining two hybrid orbitals on each carbon atom overlap with the 1s orbitals of hydrogen atoms. This forms 4 C-H sigma bonds in total (2 per carbon atom).
Summing these up:

1 (C-C sigma bond) + 4 (C-H sigma bonds) = 5 sigma bonds

4. Counting Pi (π) Bonds:
Pi bonds are formed by the lateral (sideways) overlap of unhybridized p-orbitals.
• The single unhybridized 2p orbital on each of the two carbon atoms overlap sideways with one another to form 1 pi bond.

Conclusion:
Therefore, the double bond between the two carbon atoms consists of one sigma bond and one pi bond, while the four carbon-hydrogen single bonds are all sigma bonds. This gives a total of 5 sigma (s) bonds and 1 pi (p) bonds.

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