Question Details

The isothermal bulk modulus of a gas at atmospheric pressure is

Options

A

1 mm of Hg

B

13.6 mm of Hg

C

1.013 x 10⁵ N / m²

D

2.026 x 10⁵ N / m²

Correct Answer :

1.013 x 10⁵ N / m²

Solution :

To find the isothermal bulk modulus of a gas at atmospheric pressure, we begin by defining the isothermal bulk modulus.

The bulk modulus (B) of a substance measures its resistance to uniform compression and is defined as the ratio of the infinitesimal pressure increase to the resulting relative decrease of the volume:
B=-VdPdV
where P is pressure and V is volume.

For an ideal gas undergoing an isothermal process (a process occurring at a constant temperature T), the system obeys Boyle's Law:
PV=constant

To find dPdV, we differentiate both sides of the equation PV=constant with respect to V using the product rule:
PdVdV+VdPdV=0
P+VdPdV=0
Rearranging the terms, we get:
-VdPdV=P

Substituting this back into the definition of the bulk modulus, we find that the isothermal bulk modulus (Bisothermal) of an ideal gas is equal to its pressure:
Bisothermal=P

We are given that the gas is at atmospheric pressure. The standard value of atmospheric pressure at sea level is:
P=1 atm=1.013×105 N / m2

Therefore, the isothermal bulk modulus of the gas is:
Bisothermal=1.013×105 N / m2

The correct option is 1.013 x 10⁵ N / m².

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