Question Details

N molecules each of mass m of gas A and 2N molecules each of mass 2m of gas B are contained in the same vessel at temperature T. The mean square of the velocity of molecules of gas B is v² and the mean square of x component of the velocity of molecules of gas A is w² . The ratio w²/v² is

Options

A

1

B

2

C

1/3

D

2/3

Correct Answer :

2/3

Solution :

The correct option is 2/3.

Let's understand the step-by-step physical principles and calculations to arrive at this result.

1. Mean Square Velocity of Gas B
According to the kinetic theory of gases, the mean square velocity of molecules of a gas at absolute temperature T is given by the relation:
v 2 = 3 k B T M
where kB is the Boltzmann constant and M is the mass of a single molecule of the gas.
For gas B, the mass of each molecule is mB=2m. Therefore, the mean square velocity of molecules of gas B is:
v 2 = 3 k B T 2 m     --- (Equation 1)

2. Mean Square of the x-component of Velocity of Gas A
For gas A, the mass of each molecule is m. The total mean square velocity of molecules of gas A is:
v A 2 = 3 k B T m
Since the gas molecules move randomly in all three dimensions, space is isotropic. This means the mean square velocities along the x, y, and z axes are equal:
v A x 2 = v A y 2 = v A z 2
Therefore, the mean square of the x-component of the velocity is one-third of the total mean square velocity:
v A x 2 = 1 3 v A 2 = 1 3 3 k B T m = k B T m
Given that the mean square of the x-component of velocity of gas A is represented by w2, we have:
w 2 = k B T m     --- (Equation 2)

3. Calculating the Ratio
Dividing Equation 2 by Equation 1 to find the ratio w2v2:
w 2 v 2 = k B T m 3 k B T 2 m
Simplifying the expression by cancelling the common terms kBT and m from both the numerator and the denominator:
w 2 v 2 = 1 3 2 = 2 3

Unlock Our Free Library

Access expert-curated educational resources and study materials—completely free.

Discover more resources

You may also like

Mock Tests

View All
  • JEE
  • intermediate
  • 3 hours
  • chemistry, mathematics, physics

  • JEE
  • intermediate
  • 3 hours
  • chemical engineering, mathematics, physics