K2Cr2O7 + H2O2 + H2SO4 compound ‘X’ X is a chromium compound, what is the oxidation state of chromium in compound ‘X’.
Correct Answer :
Solution :
The correct answer is +6.
Step-by-step Explanation:
1. Identify the reaction and Compound 'X':
When potassium dichromate () reacts with hydrogen peroxide () in an acidic medium (such as ) in the presence of ether under cold conditions, a deep blue colored chromium compound 'X' is formed.
This blue compound 'X' is chromium pentoxide (also known as chromium oxide peroxide), which has the molecular formula . The ether layer helps to stabilize this otherwise unstable blue-colored compound.
2. Analyze the chemical structure of :
Chromium pentoxide () has a unique butterfly-like structure. In this molecule:
- There is one oxo oxygen atom that is double-bonded directly to the chromium atom (). This oxygen atom has a standard oxidation state of -2.
- There are four peroxide oxygen atoms forming two peroxide linkages () bonded to the chromium atom. Each oxygen atom involved in a peroxide linkage has an oxidation state of -1.
3. Calculate the oxidation state of chromium (Cr) in :
Let the oxidation state of chromium be represented as .
Since is a neutral molecule, the sum of the oxidation states of all the atoms in it must be equal to 0.
Simplifying the equation:
Therefore, the oxidation state of chromium in compound 'X' () is +6.
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