Question Details

K2Cr2O7 + H2O2 + H2SO4 c o n d i t i o n s e t h e r c o l d compound ‘X’ X is a chromium compound, what is the oxidation state of chromium in compound ‘X’.

Options

A

+6

B

+3

C

+5

D

+10

Correct Answer :

+6

Solution :

The correct answer is +6.

Step-by-step Explanation:

1. Identify the reaction and Compound 'X':
When potassium dichromate (K2Cr2O7) reacts with hydrogen peroxide (H2O2) in an acidic medium (such as H2SO4) in the presence of ether under cold conditions, a deep blue colored chromium compound 'X' is formed.
This blue compound 'X' is chromium pentoxide (also known as chromium oxide peroxide), which has the molecular formula CrO5. The ether layer helps to stabilize this otherwise unstable blue-colored compound.

2. Analyze the chemical structure of CrO5:
Chromium pentoxide (CrO5) has a unique butterfly-like structure. In this molecule:
- There is one oxo oxygen atom that is double-bonded directly to the chromium atom (Cr=O). This oxygen atom has a standard oxidation state of -2.
- There are four peroxide oxygen atoms forming two peroxide linkages (-O-O-) bonded to the chromium atom. Each oxygen atom involved in a peroxide linkage has an oxidation state of -1.

3. Calculate the oxidation state of chromium (Cr) in CrO5:
Let the oxidation state of chromium be represented as x.
Since CrO5 is a neutral molecule, the sum of the oxidation states of all the atoms in it must be equal to 0.

x + 1 × - 2 + 4 × - 1 = 0

Simplifying the equation:

x - 2 - 4 = 0

x - 6 = 0

x = + 6

Therefore, the oxidation state of chromium in compound 'X' (CrO5) is +6.

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