Question Details

How many orbitals can have the following set of quantum numbers, n = 3, l = 1, m1 = 0 ?

Options

A

1

B

2

C

3

D

4

Correct Answer :

1

Solution :

The correct option is 1.

To understand why this is the correct answer, let us break down the set of quantum numbers provided in the question:
The quantum numbers given are:
- Principal quantum number, n = 3
- Azimuthal (or orbital angular momentum) quantum number, l = 1
- Magnetic quantum number, ml = 0

Each unique combination of the three quantum numbers (n, l, and ml) corresponds to exactly one specific atomic orbital.

Let us analyze these quantum numbers step-by-step:

1. The principal quantum number, n = 3, specifies the third main energy level or shell.

2. The azimuthal quantum number, l = 1, specifies the subshell. For l = 1, this corresponds to a p-subshell (specifically, the 3p subshell since n = 3).

3. The magnetic quantum number, ml, describes the spatial orientation of the orbital within a subshell. For a p-subshell (l = 1), the possible values for ml are:
ml = -1, 0, +1
This means there are three separate p-orbitals in the 3p subshell, corresponding to these three spatial orientations.

4. The question specifies a single, definite value for the magnetic quantum number: ml = 0. This restricts us to one specific orbital out of the three available in the 3p subshell (often designated as the 3pz orbital).

Since all three spatial quantum numbers (n, l, ml) are fully defined, they describe a single, unique orbital. Therefore, only 1 orbital can have this specific set of quantum numbers.

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