For irreversible expansion of an ideal gas under isothermal condition, the correct option is :
Correct Answer :
∆U=0, ∆Sᵗᵒᵗᵃˡ≠0
Solution :
The correct option is ∆U=0, ∆Sᵗᵒᵗᵃˡ≠0.
Let us analyze the thermodynamic behavior of an ideal gas undergoing an irreversible expansion under isothermal conditions step-by-step:
1. Internal Energy Change () of an Ideal Gas:
For an ideal gas, the internal energy () is a function of temperature only. Since the process is carried out under isothermal conditions, the temperature remains constant ( or ).
Therefore, the change in internal energy is:
2. Total Entropy Change ():
According to the second law of thermodynamics, for any spontaneous, irreversible process, the total entropy of the universe (system + surroundings) must increase:
Since the expansion of the gas is irreversible, the total entropy change cannot be zero. Thus:
Combining these two results, we get:
and
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