Question Details

Find the temperature at which the rate of effusion of N₂ is 1.625 times to that of SO₂ at 500℃

Options

A

620℃

B

173℃

C

110℃

D

373℃

Correct Answer :

620℃

Solution :

The correct option is 620℃.

According to Graham's law of effusion, the rate of effusion of a gas (r) is directly proportional to its temperature in Kelvin (T) and inversely proportional to the square root of its molar mass (M).
This relationship can be expressed mathematically as:
rTM

Let us write down the given parameters and constants:
For nitrogen gas (N2):
Molar mass, MN2=28 g/mol
Let its temperature be TN2 in Kelvin.
For sulfur dioxide gas (SO2):
Molar mass, MSO2=32+2(16)=64 g/mol
Temperature, TSO2=500=500+273=773 K

The ratio of the rate of effusion of N2 to that of SO2 is:
rN2rSO2=TN2TSO2×MSO2MN2

Given that the rate of effusion of N2 is 1.625 times that of SO2:
rN2rSO2=1.625

Substitute the values into the equation:
1.625=TN2773×6428

Squaring both sides to remove the square root:
(1.625)2=TN2773×167
2.640625=TN2×165411

Solving for TN2:
TN2=2.640625×541116
TN2893 K

Convert the temperature from Kelvin back to Celsius:
Temperature in =893-273=620

Therefore, the temperature at which the rate of effusion of N2 is 1.625 times that of SO2 is 620℃.

Unlock Our Free Library

Access expert-curated educational resources and study materials—completely free.

Discover more resources

You may also like

Mock Tests

View All
  • JEE
  • intermediate
  • 3 hours
  • chemistry, mathematics, physics

  • JEE
  • intermediate
  • 3 hours
  • chemistry, mathematics, physics