Question Details

Find the fraction of the total pressure exerted by hydrogen if it is mixed with ethane in an empty container at 25℃

Options

A

1/16

B

15/16

C

1/2

D

1

Correct Answer :

15/16

Solution :

The correct option is 15/16.

To understand why this is the correct fraction, let us analyze the properties of the gases involved in the mixture under the given conditions.
When two gases are mixed in a container, their pressures are related to their mole fractions according to Dalton's Law of Partial Pressures. The fraction of the total pressure exerted by a gas is equal to its mole fraction in the mixture.

Let the mass of hydrogen (H2) and ethane (C2H6) mixed in the container be equal, say w grams each.

The molar mass of hydrogen (H2) is:
MH2=2 g/mol

The molar mass of ethane (C2H6) is:
MC2H6=(2×12)+(6×1)=30 g/mol

Now, we calculate the number of moles (n) for each gas:
Moles of hydrogen, nH2=w2
Moles of ethane, nC2H6=w30

The total number of moles in the mixture is:
ntotal=nH2+nC2H6=w2+w30
ntotal=15w+w30=16w 30

According to Dalton's Law of Partial Pressures, the fraction of the total pressure exerted by hydrogen is equal to its mole fraction:
XH2=nH2ntotal
XH2=w216w30=w2×3016w=1516

Therefore, the fraction of the total pressure exerted by hydrogen in the mixture is 15/16.

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