Find product P of the following reaction.
Correct Answer :
Solution :
Correct Answer: Option 3
Let's analyze the step-by-step chemical reaction sequence starting from styrene (vinylbenzene) as shown in the question image to find the major product P.
Step 1: Acid-catalyzed hydration of Styrene
The starting material is styrene, which has a vinyl group () attached to a benzene ring.
When treated with dilute acid (), an electrophilic addition reaction occurs following Markovnikov's rule:
1. Protonation of the alkene double bond occurs to form the more stable benzylic carbocation intermediate (), which is highly stabilized by resonance with the aromatic ring.
2. Water acts as a nucleophile and attacks the carbocation, followed by deprotonation to yield a secondary alcohol: 1-phenylethanol ().
Step 2: Oxidation with Chromic Acid
The secondary alcohol, 1-phenylethanol, is treated with chromic acid (), which is a strong oxidizing agent.
This reagent oxidizes secondary alcohols into ketones. Therefore, 1-phenylethanol is oxidized to acetophenone ().
Step 3: Wolff-Kishner Reduction
Finally, acetophenone is treated with hydrazine () in the presence of concentrated potassium hydroxide (). This is the classic Wolff-Kishner reduction:
1. Hydrazine reacts with the carbonyl group of acetophenone to form a hydrazone intermediate ().
2. Under strongly basic conditions with heating, the hydrazone undergoes deprotonation and elimination of nitrogen gas (), reducing the ketone group () directly to a methylene group ().
3. The resulting major product P is ethylbenzene ().
Comparing this structure with the options provided, Option 3 shows ethylbenzene.
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