Ethylene diaminetetraacetate (EDTA) ion is :
Correct Answer :
Hexadentate ligand with four “O” and two “N” donor atoms
Solution :
The correct answer is: Hexadentate ligand with four “O” and two “N” donor atoms.
Step-by-step Explanation:
1. Concept of Denticity:
Denticity refers to the number of donor atoms that a single ligand uses to bind to a central metal atom or ion in a coordination complex. Based on the number of donor atoms, ligands are classified as monodentate (one donor atom), bidentate (two donor atoms), tridentate (three donor atoms), and so on.
2. Structure of EDTA4-:
Ethylenediaminetetraacetate (EDTA4-) is a coordinate ligand synthesized by replacing the hydrogen atoms of ethylenediamine with four acetate groups. The structure of the EDTA4- ion is represented as:
3. Identifying the Donor Atoms:
Within a single EDTA4- ion, there are two types of atoms that have lone pairs of electrons available to coordinate with a central metal ion:
4. Conclusion:
Because EDTA4- possesses a total of six donor atoms (two nitrogen atoms and four oxygen atoms) that can bind simultaneously to a metal ion, it functions as a hexadentate ligand.
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