Question Details

At what temperature is the root mean square velocity of gaseous hydrogen molecules is equal to that of oxygen molecules at 47°C

Options

A

20 K

B

80 K

C

-73 K

D

3 K

Correct Answer :

20 K

Solution :

The correct option is 20 K.

Step-by-Step Explanation:

1. Recall the formula for Root Mean Square (RMS) Velocity:
The root mean square velocity (vrms) of a gaseous molecule is given by the formula:
vrms=3RTM
where:
- R is the universal gas constant,
- T is the absolute temperature (in Kelvin), and
- M is the molar mass of the gas.

2. Set up the condition given in the problem:
We are given that the RMS velocity of hydrogen molecules (H2) at an unknown temperature TH2 is equal to the RMS velocity of oxygen molecules (O2) at 47°C.
vrms(H2)=vrms(O2)

3. Convert temperatures and gather molar masses:
- Temperature of oxygen, TO2=47°C=47+273=320 K
- Molar mass of hydrogen gas (H2), MH2=2 g/mol
- Molar mass of oxygen gas (O2), MO2=32 g/mol

4. Equate the two velocities:
3RTH2MH2=3RTO2MO2

Squaring both sides and simplifying by canceling the common factor 3R:
TH2MH2=TO2MO2

5. Calculate the unknown temperature (TH2):
Substitute the known values into the equation:
TH22=32032
TH22=10
TH2=10×2=20 K

Thus, the root mean square velocity of hydrogen molecules at 20 K is equal to that of oxygen molecules at 47°C.

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