Question Details

An ideal gas is expanded isothermally at 300 K from 1 litre to 10 litres. Find the ΔE for this process (R = 2 cal mol⁻¹ K⁻¹)

Options

A

9 L atm

B

1381.1 cal

C

zero

D

163.7 cal

Correct Answer :

zero

Solution :

The correct option is "zero".

To understand why the change in internal energy (ΔE or ΔU) is zero, let us look at the thermodynamic properties of an ideal gas.

For an ideal gas, the internal energy is a function of temperature only. Mathematically, this is expressed as:
E=f(T)
where E is the internal energy and T is the absolute temperature.

The change in internal energy for n moles of an ideal gas during any process is given by the formula:
ΔE=nCvΔT
where Cv is the molar heat capacity at constant volume, and ΔT is the change in temperature (ΔT=Tfinal-Tinitial).

In this problem, the gas is expanded isothermally. An isothermal process is one that occurs at a constant temperature. Therefore:
T=300 K=constant
Consequently, the change in temperature is:
ΔT=0

Substituting ΔT=0 into the internal energy equation:
ΔE=nCv(0)=0

Therefore, the change in internal energy (ΔE) for this isothermal expansion of an ideal gas is indeed zero.

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