Question Details

Alkaline KMnO4 oxidises Iodide to a particular product (A). Determine the oxidation state of Iodine in compound (A).

Options

A

+2

B

+3

C

+5

D

+7

Correct Answer :

+5

Solution :

To determine the oxidation state of iodine in the product formed when alkaline potassium permanganate (KMnO4) oxidizes iodide ions (I-), let us look at the chemical reaction in detail.

In an alkaline or faint/mildly basic medium, potassium permanganate (KMnO4) acts as a strong oxidizing agent. It oxidizes iodide (I-) to iodate ions (IO3-).
The balanced chemical equation for this redox reaction is:
2MnO4-+I-+H2O2MnO2+IO3-+2OH-

From this reaction, the compound (A) containing iodine is the iodate ion, IO3-.

Now, let us calculate the oxidation state of iodine in the iodate ion (IO3-):
Let the oxidation state of iodine (I) be x.
We know that the oxidation state of oxygen (O) is typically -2.
Since the overall charge on the iodate ion is -1, we can write the algebraic equation:
x+3(-2)=-1
x-6=-1
x=-1+6
x=+5

Thus, the oxidation state of iodine in compound (A) is +5.

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