Alkaline KMnO4 oxidises Iodide to a particular product (A). Determine the oxidation state of Iodine in compound (A).
Correct Answer :
Solution :
To determine the oxidation state of iodine in the product formed when alkaline potassium permanganate () oxidizes iodide ions (), let us look at the chemical reaction in detail.
In an alkaline or faint/mildly basic medium, potassium permanganate () acts as a strong oxidizing agent. It oxidizes iodide () to iodate ions ().
The balanced chemical equation for this redox reaction is:
From this reaction, the compound (A) containing iodine is the iodate ion, .
Now, let us calculate the oxidation state of iodine in the iodate ion ():
Let the oxidation state of iodine () be .
We know that the oxidation state of oxygen () is typically -2.
Since the overall charge on the iodate ion is -1, we can write the algebraic equation:
Thus, the oxidation state of iodine in compound (A) is +5.
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