Question
In the vicinity of the triple point, the equation of liquid-vapour boundary in the π· β π» phase diagram for ammonia is π₯π§ π· = ππ. ππ β ππππ/π», where P is pressure (in Pa) and π» is temperature (in K). Similarly, the solid-vapour boundary is given by π₯π§ π· = ππ. ππ β ππππ/π». The temperature at the triple point is ___________ K (round off to one decimal place).
Answer :
Correct answer is : 195.19
At triple point temperature of solid, liquid and vapour is same
β΄ Equating
Now,
Multiplying by βTβ on both sides
24.38 T β 3063 = 27.92 T β 3754
3.54 T = 691
T = 195.197 K
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